Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

Double–double radio galaxies: remnants of merged supermassive binary black holes     

F. K. Liu  Xue-Bing Wu  S. L. Cao 《Monthly notices of the Royal Astronomical Society》2003,340(2):411-416

  相似文献   

CHANGE　OF　NUTRIENT　IMPORT　AND　EXPORT　IN　PROCESS　OF　RAINFALL　IN　AILAO　MOUNTAIN　OF　YUNNAN　PROVINCE     

甘健民  薛敬意  赵恒康 《中国地理科学(英文版)》1996,6(2):155-165

ＣＨＡＮＧＥ　ＯＦ　ＮＵＴＲＩＥＮＴ　ＩＭＰＯＲＴ　ＡＮＤ　ＥＸＰＯＲＴ　ＩＮ　ＰＲＯＣＥＳＳ　ＯＦ　ＲＡＩＮＦＡＬＬ　ＩＮ　ＡＩＬＡＯ　ＭＯＵＮＴＡＩＮ　ＯＦ　ＹＵＮＮＡＮ　ＰＲＯＶＩＮＣＥＧａｎＪｉａｎｍｉｎ（甘健民）；ＸｕｅＪｉｎｇｙｉ（薛敬意...  相似文献   

关于高速滑坡的几个问题     

冯希杰  张骏 《地球科学与环境学报》1987,(4)

高速滑坡问题是当前工程地质和环境地质学界极为关注的问题。本文对诸如滑体高速滑动所对应的时空界限、滑体滑动过程所产生的热效应以及空气浮托力等高速滑坡产生机制问题进行了初步探讨。  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

  相似文献   

山东地质环境中砷的分布特征          下载免费PDF全文

孔庆友 《山东国土资源》2004,20(5):37-42

山东地质环境砷含量一般为(10^-6)：各类岩石4．87～7．89，土壤10．89，水系底泥6．23。根据砷的分布特点。总体上可将山东分为鲁中南-鲁东山地丘陵区、鲁西北-鲁西南平原区2个大的砷的地质环境(背景)区及7个亚区。每个亚区内，山地丘陵区砷的地球化学背景较低，而平原区砷的背景相对高些。但总体上，全省处于正常的和相对比较低的背景，还未发现原生地质环境形成高砷背景对人体危害的案例。  相似文献   

Revised masses of dust and gas of SCUBA Local Universe Survey far-infrared bright galaxies based on a recent CO survey     

Ernest Seaquist  Lihong Yao  Loretta Dunne  Heather Cameron 《Monthly notices of the Royal Astronomical Society》2004,349(4):1428-1434

  相似文献   

双极化天气雷达方程     

董豹  王贤勤 《成都信息工程学院学报》1996,(3)

在回转椭球状降水粒子的假设下求出了降水粒子的散射截面，并且考虑了粒子轴线铅垂和随机取向两种重要的典型情况；推导了双极化雷达的回波方程以及降雨量公式。该方程除包含降水粒子的信息外，关于雷达与降水粒子间的几何关系都以雷达天线仰角及雷达与降水粒子间的距离表示，同时还考虑了地球的球面效应和大气折射效应。由于采用了并矢方法，使推导简捷明了  相似文献   

西南矿区山体崩塌成因机制分析及防治对策   总被引：1，自引：0，他引：1  

杜蜀宾 《地球科学与环境学报》2004,26(1):89-92

西南地区的矿区具有相似的地理、地质环境,通过四川芙蓉煤矿白岩崩塌的典型实例,对西南矿区山体崩塌的成灾环境进行调查研究,揭示了西南矿区山体崩塌的成因机制,并简要提出了对该煤矿开发与综合治理建议,指出了加强防治工作的紧迫性,强调开展系统工程防灾的重要性,并为该煤矿解决正常采掘接替及工作面的布置问题作出了科学的指导.  相似文献